The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Profile photo of Hossein Hashemi

Hossein Hashemi

Researcher

Profile photo of Hossein Hashemi

Transport and retention of functionalized graphene oxide nanoparticles in saturated/unsaturated porous media : Effects of flow velocity, ionic strength and initial particle concentration

Author

  • Mahsa Shahi
  • Mohammad Reza Alavi Moghaddam
  • Seiyed Mossa Hosseini
  • Hossein Hashemi
  • Magnus Persson
  • Elaheh Kowsari

Summary, in English

The widespread use of nanomaterials has raised the threat of nanoparticles (NPs) infection of soils and groundwater resources. This research aims to investigate three parameters including flow velocity, ionic strength (IS), and initial particle concentration effects on transport behavior and retention mechanism of functionalization form of graphene oxide with polyvinylpyrrolidone (GO-PVP). The transport of GO-PVP was investigated in a laboratory-scale study through saturated/unsaturated (Saturation Degree = 0.91) sand columns. Experiments were conducted on flow velocity from 1.20 to 2.04 cm min−1, initial particle concentration from 10 to 50 mg L−1, and IS of 5–20 mM. The retention of GO-PVP was best described using the one-site kinetic attachment model in HYDRUS-1D, which accounted for the time and depth-dependent retention. According to breakthrough curves (BTCs), the lower transport related to the rate of mass recovery of GO-PVP was obtained by decreasing flow velocity and initial particle concentration and increasing IS through the sand columns. Increasing IS could improve the GO-PVP retention (based on katt and Smax) in saturated/unsaturated media; katt increases from 2.81 × 10−3 to 3.54 × 10−3 s−1 and Smax increases from 0.37 to 0.42 mg g−1 in saturated/unsaturated conditions, respectively. Our findings showed that the increasing retention of GO-PVP through the sand column under unsaturated condition could be recommended for the reduction of nanoparticles danger of ecosystem exposure.

Department/s

  • Division of Water Resources Engineering
  • MECW: The Middle East in the Contemporary World
  • LTH Profile Area: Water

Publishing year

2024-04

Language

English

Publication/Series

Chemosphere

Volume

354

Document type

Journal article

Publisher

Elsevier

Topic

  • Water Engineering

Keywords

  • Breakthrough curves
  • GO-PVP
  • HYDRUS-1D
  • One-site kinetic attachment model
  • Retention mechanism
  • Transport behavior

Status

Published

ISBN/ISSN/Other

  • ISSN: 0045-6535